flammable liquids are incompatible with oxidizers

Picric acid can form explosive salts with many metals, or by itself when dry. SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION Exposure Guidelines: INGREDIENTS EXPOSURE LIMITS Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.Reaction with water or moist air may release toxic, corrosive or flammable gases. Pyrophoric liquids, solids and gases, nondetonable. Use approved equipment, including labelled safety containers, for flammable and combustible liquids. H225: Highly Flammable liquid and vapor [Danger Flammable liquids] H304: May be fatal if swallowed and enters airways [Danger Aspiration hazard] H315: Causes skin irritation [Warning Skin corrosion/irritation] H336: May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects] Organic peroxides, Class I. Oxidizers, Class 3, that are used or stored in normally open containers or systems, or in closed containers or systems pressurized at more than 15 pounds per square inch gauge (103 kPa). to confirm spill areas. These flammable or explosive gases can form when CO2 extinguishers are used to fight hydride fires. Always store flammable materials in a flammable storage cabinet, even if the chemical has other hazards. Keep container closed when not in use. For electric isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Oxidizers and flammable gases should be kept at least 20 ft. away from combustible materials and/or incompatible gases or substances. Contact with metals may evolve flammable hydrogen gas. 3 396 170, 1968]. Diesel Fuel January 23, 2015 Page 4 of 7 SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION Avoid storage on wood floors. Flammable liquids also need to be stored at least 25 from oxidizers and Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. When heated to decomposition, it emits highly toxic fumes of oxides of sulfur. Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]: DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. reclamation or disposal. CHLORINE TRIFLUORIDE is a low-boiling liquid (b.p. Store away from oxidizers and other incompatible materials. Protect containers from physical damage. Store away from oxidizers and other incompatible materials. Use appropriate personal protective equipment (PPE): Wear closed-toed shoes that cover the feet. storage of flammable liquids. Use only the quantity needed at the time. Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. Use approved containers for disposal of rags and other work. TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. No information available. This also means storing certain chemical groups away from other chemical groups like oxidizers and flammables. Flammable gases. Flammable liquids - * Flammable solids - * Self-reactive substances and mixtures - * Pyrophoric liquids - * Incompatible materials: Oxidizing agents, amines, strong bases. Store away from oxidizers and other incompatible materials. Consider wind direction; stay upwind and uphill, if possible. The gas is heavier than air and may travel along the ground to an ignition source. Tetrazoles include, 2-methyl, 2-ethyl, 5-ethyl, 2-methyl-5-vinyl, 5-amino-2-ethyl [US Pat. Contact with metals may evolve flammable hydrogen gas. Types of reagents are precipitants, solvents, oxidizers, reducers, fluxes, and colorimetric reagents. 12 C) which is irritating and toxic in the gaseous state. An inventory of all chemicals must be maintained. Store flammable and combustible liquids away from incompatible materials (e.g., oxidizers). Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Some are TIH materials themselves, e.g., chlorine, borides, and phosphides to generate toxic or flammable gases. The absorption and excretion of (14)C-benzoyl chloride was studied in male and female Holtzman albino rats. Ingredients shall not be stored with incompatible materials. storage of flammable liquids. Store, handle and use flammable and combustible liquids in well-ventilated areas. Forms explosive complexes with ether, dimethylamine and various tetrazoles. Oxidizers (e.g., nitrates, perchlorates, bromates, permanganates, peroxides, iodates) Organic Peroxides (e.g., benzoyl peroxide, cumene hydroperoxide, methyl ethyl ketone peroxide) Corrosivity. Ground and bond the drum and receiving vessel when transferring flammable liquids from a drum to prevent static charge buildup. Avoid inhalation. For example, aldehydes are both flammable and toxic. Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: CAUTION: The majority of these products have a very low flash point. It is incompatible with fuels and nitro compounds. Containers may explode when heated. Be familiar with materials Dry Ice is incompatible with. 1910.109(h)(3)(iii)(e) Peroxides and chlorates shall not be used. Keep away from reducing agents. storage of flammable liquids. The graphic above shows that flammable liquids have a flashpoint below 100 F (37.8 C). Phosphine is a colorless, flammable, and explosive gas at ambient temperature that has the odor of garlic or decaying fish. Incompatible with many materials including strong oxidizers, metals, strong nitric acid, bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, 7.2.4 Oxidizers 7.2.5 Poisons 7.2.6 Explosives or unstable reactives, such as picric acid. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Store in a cool, dry, well-ventilated area away from incompatible substances. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Protect containers from physical damage. Protect containers from physical damage. Combustible liquids have a flashpoint above 100 F. Never store incompatible liquids near one another. Oxidizers (Yellow letters on black background). Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. During the purging of the pipeline, a volume of nitrogen equivalent to approximately 1/2 tank volume had been injected near the base of the tank. GHS Hazard Statements: H225: Highly Flammable liquid and vapor [Danger Flammable liquids]H302: Harmful if swallowed [Warning Acute toxicity, oral]H312: Harmful in contact with skin [Warning Acute toxicity, dermal]H315: Causes skin irritation [Warning Skin corrosion/irritation]H319: Causes serious eye irritation [Warning Serious eye damage/eye CAUTION: Hydrogen (), Deuterium (), Hydrogen, refrigerated liquid and Hydrogen and Methane mixture, compressed will burn with an invisible flame.Use an alternate method of detection (thermal camera, broom Avoid skin contact with Dry Ice. Interaction with water is violent and may be explosive, even with ice [Sidgwick, 1950, p. 1156]. Spills But, flammability trumps toxicity. corrosive or flammable SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION Exposure Guidelines: INGREDIENTS EXPOSURE LIMITS Specific Waste Management Requirements 5.2 Chemical Waste Management 5.2.1 Definition 5.2.2 Packaging 5.2.3 Labelling 5.2.4 Storage 5.2.5 Special Cases 5.2.6 Collection Schedule Chemical wastes are not treated on campus; the majority are recycled. Containers may explode when heated. It is incompatible with other storage groups and should be stored seperately. A highly reactive oxidant, it is spontaneously flammable and used as a rocket propellant. An investigation revealed that the storage tank did not contain any residual contamination from previous products and the 1,1,1-trichloroethane was not contaminated with highly flammable liquids. During work: Perform all operations in a well-ventilated area. It contains some of the more common incompatible materials. Contact with metals may evolve flammable hydrogen gas. The oxidation state, which describes the degree of An explosion resulted [MCA Case History 128(1962)] Incompatible with strong oxidizers. When flammable liquids are stored with other materials, care needs to be taken to separate them from any incompatible materials by a distance of at least 20 feet or by a partition. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. While it is always best to segregate, acetic acid can be stored other flammable liquids. Evacuate nonessential personnel and remove or secure all ignition sources. For electric isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Containers may explode when heated. Laboratory Hazardous Waste Management and Disposal Manual 5. An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent (called the reductant, reducer, or electron donor).In other words, an oxidizer is any substance that oxidizes another substance. This can lead to frostbite. Cryogenic fluids, flammable. [Flammable Liquids (Water-Immiscible)]: For electric vehicles or equipment, ERG (150 feet) for liquids and at least 25 meters (75 feet) for solids. Of the organic wastes produced, 100% are recycled through Keep away from flammable liquids. The following list is not a complete listing of incompatible materials. Secure it to prevent unauthorized access. Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. Contact with metals may evolve flammable hydrogen gas. Evaluate the direction of product travel, diking, sewers, etc. Examples of Incompatible Chemicals. Inventories must include the full chemical name, location of storage, and associated hazard (e.g. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Store in a dry, well ventilated area away from heat, direct sunlight and all sources of ignition. For electric vehicles or equipment, ERG (150 feet) for liquids and at least 25 meters (75 feet) for solids. Emergency Measures. Reaction with water may generate much heat that will increase Belongs to the Following Reactive Group(s) Hydrocarbons, Aliphatic Saturated; Potentially Incompatible Absorbents. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Esters react with acids to liberate heat along with alcohols and acids. 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